Swelling kinetics of the onion phase

A theory is presented for the behavior of an array of multi-lamellar vesicles (the onion phase) upon addition of solvent. A unique feature of this system is the possibility to sustain pressure gradients by tension in the lamellae. Tension enables the onions to remain stable beyond the unbinding point of a flat lamellar stack. The model accounts for various concentration profiles and interfaces developing in the onion as it swells. In particular, densely packed ‘onion cores’ are shown to appear, as observed in experiments. The formation of interfaces and onion cores may represent an unusual example of stabilization of curved interfaces in confined geometry. PACS. 83.70.Hq Heterogeneous liquids: suspensions, dispersions, emulsions, pastes, slurries, foams, block copolymers, etc. – 87.16.Dg Membranes, bilayers, and vesicles – 82.65.Dp Thermodynamics of surfaces and interfaces